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New 4-(trifluoromethyl)tetrahydrothiophenes containing an ester, sulfone, sulfoximine, sulfonamide, or phosphonate moiety at position 3 were synthesized by 1,3-dipolar [3 + 2]-cycloaddition reactions of 3,3,3-trifluoropropene derivatives and thiocarbonyl ylide generated in situ from… Click to show full abstract
New 4-(trifluoromethyl)tetrahydrothiophenes containing an ester, sulfone, sulfoximine, sulfonamide, or phosphonate moiety at position 3 were synthesized by 1,3-dipolar [3 + 2]-cycloaddition reactions of 3,3,3-trifluoropropene derivatives and thiocarbonyl ylide generated in situ from chloromethyl trimethylsilylmethyl sulfide. GRAPHICAL ABSTRACT
Keywords:
tetrahydrothiophenes via;
cycloaddition reactions;
functional substituted;
substituted trifluoromethyl;
trifluoromethyl tetrahydrothiophenes
Journal Title: Journal of Sulfur Chemistry
Year Published: 2019
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Journal Title: Journal of Sulfur Chemistry
Year Published: 2019
Link to full text (if available)
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recommendations!