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NiCo2S4 nanosheets grafted SiO2@C core-shelled spheres for high performance supercapacitors.

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A high-performance electrode for supercapcitors has been prepared by growing NiCo2S4 (NCS) nanosheets on SiO2@C core-shell nanospheres (SiO2@C-NCS nanocomposite) using simple yet effective solution-based method. Benefiting from the considerable combination… Click to show full abstract

A high-performance electrode for supercapcitors has been prepared by growing NiCo2S4 (NCS) nanosheets on SiO2@C core-shell nanospheres (SiO2@C-NCS nanocomposite) using simple yet effective solution-based method. Benefiting from the considerable combination and unique mesoporous structure with high surface area, SiO2@C-NCS nanocomposite as an electrode material for supercapacitor exhibited long-term stable cycling performance with high specific capacitance of 625 F g-1 at 1 mA cm-2. An asymmetric supercapcitor (ASC) assembled with SiO2@C-NCS as positive electrode and carbon nanotube paper (CNP) as negative electrode in aquoeous KOH solution can be cycled in a high-voltage region of 1.6 V, which resulted in a high energy density of 16 Wh kg-1 at an ultra-high specific power of 7200 W kg-1. These promising results suggest the possible application of mixed transition metal sulfides-based composites in high-performance asymmetric supercapacitors.

Keywords: sio2 core; sio2 ncs; performance; electrode; high performance

Journal Title: Nanotechnology
Year Published: 2019

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