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The α-Fe2O3/graphite anode composites with enhanced electrochemical performance for lithium-ion batteries.

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The α-Fe2O3/graphite composites were prepared by a thermal decomposition method using the expanded graphite as matrix. The α-Fe2O3 nanoparticles with the size of 10-30 nm were embedded into interlayers of… Click to show full abstract

The α-Fe2O3/graphite composites were prepared by a thermal decomposition method using the expanded graphite as matrix. The α-Fe2O3 nanoparticles with the size of 10-30 nm were embedded into interlayers of graphite, forming a laminated porous nanostructure with a main pore distribution from 2 to 20 nm and the BET surface area of 33.54 m2 g-1. The porous structure constructed by the graphite sheets can alleviate the adverse effects caused by the huge volume change of the α-Fe2O3 grains during the charge/discharge process. The composite electrode exhibits a high reversible capacity of 1588 mAh g-1 after 100 cycles at 100 mA g-1, 702 mAh g-1 at 5A g-1, 460 mAh g-1 at 10A g-1 after 160 cycles, respectively, showing good cycle stability and outstanding rate capability at high current densities.

Keywords: electrochemical performance; fe2o3 graphite; anode composites; graphite anode; composites enhanced; enhanced electrochemical

Journal Title: Nanotechnology
Year Published: 2020

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