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White-light emission in Yb3+/Er3+/Tm3+- and Yb3+/Er3+/Tm3+/Ho3+-doped α-NiMoO4 nanoparticles

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Yb3+/Er3+/Tm3+- and Yb3+/Er3+/Tm3+/Ho3+-doped α-NiMoO4 nanoparticles were synthesized using a microwave hydrothermal method and studied for white-light emission under 980 nm laser diode excitation. White upconversion (UC) light was successfully obtained… Click to show full abstract

Yb3+/Er3+/Tm3+- and Yb3+/Er3+/Tm3+/Ho3+-doped α-NiMoO4 nanoparticles were synthesized using a microwave hydrothermal method and studied for white-light emission under 980 nm laser diode excitation. White upconversion (UC) light was successfully obtained with the appropriate control of blue, green, and red emissions by successfully tuning the Er3+ and Ho3+ concentrations in Yb3+/Er3+/Tm3+- and Yb3+/Er3+/Tm3+/Ho3+-doped α-NiMoO4, respectively. In addition, the white color emission was shown by the CIE chromaticity coordinates of samples. The energy transfer mechanisms are explained in detail based on the emission spectra and pump power density-dependent UC luminescence intensity in rare earth (Yb3+/Er3+/Tm3+ and Yb3+/Er3+/Tm3+/Ho3+)-doped α-NiMoO4 nanoparticles. The results indicate that Yb3+/Er3+/Tm3+- and Yb3+/Er3+/Tm3+/Ho3+-doped α-NiMoO4 nanoparticles can be good candidates for white-light devices.

Keywords: ho3; yb3 er3; er3 tm3

Journal Title: Nanotechnology
Year Published: 2022

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