LAUSR

The distinctive shape of an icicle is the outcome of a highly non-equilibrium process involving heat and mass transport in the presence of fluid flowing over an evolving topography. It has previously been shown that the ripple patterns with a near universal wavelength that are observed on many icicles are correlated with small levels of impurities in the feed water. Models of icicle shape evolution, and of the origin of the ripple pattern, require a detailed understanding of how liquid water flows over a growing icicle. The impurity effect is not accounted for by any existing model of ripple formation. Here, we explore this flow dynamics using laboratory-grown icicles with a fluorescent dye as an impurity. Contrary to previous models, we find that the ice is incompletely wetted by the liquid phase, and that the whole process is much more stochastic than has been previously assumed. In addition, the presence of impurities modifies the wetting properties of the ice surface, while the emerging topography interacts with the liquid distribution. There is evidence for mixed-phase ice. These observations must inform any successful model of an impurity-driven rippling instability. Our results have general implications for the morphological evolution of many natural, gravity-driven, wet ice growth processes. Video Abstract: Experiments on the dynamic wetting of growing icicles