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Segregations and desorptions of Ge atoms in nanocomposite Si 1-x Ge x films during high-temperature annealing

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Nanocomposite Si1−x Ge x films are deposited by dual-source jet-type inductively coupled plasma chemical vapor deposition (jet-ICPCVD). The segregations and desorptions of Ge atoms, which dominate the structural evolutions of… Click to show full abstract

Nanocomposite Si1−x Ge x films are deposited by dual-source jet-type inductively coupled plasma chemical vapor deposition (jet-ICPCVD). The segregations and desorptions of Ge atoms, which dominate the structural evolutions of the films during high-temperature annealing, are investigated. When the annealing temperature ( is 900 °, the nanocomposite Si1−x Ge x films are well crystallized, and nanocrystals (NCs) with the core-shell structure form in the films. After being annealed at 1000 °C (above the melting point of bulk Ge), Ge atoms accumulate on the surfaces of Ge-rich films, whereas pits appear on films with lower Ge content, resulting from desorption. Meanwhile, voids are observed in the films. A cone-like structure involving the percolation of the homogeneous clusters and the crystallization of NCs enhances Ge segregation.

Keywords: segregations desorptions; desorptions atoms; temperature; high temperature; temperature annealing; films high

Journal Title: Chinese Physics B
Year Published: 2017

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