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Subtle lattice distortion driven phase transitions in layered ACu4As2(A=Eu,Sr)

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The compounds composed of transition meatal cations and pnictide anions provide a rich platform for novel physical phenomena. Here we report the observation of a phase transition at ~ 70… Click to show full abstract

The compounds composed of transition meatal cations and pnictide anions provide a rich platform for novel physical phenomena. Here we report the observation of a phase transition at ~ 70 K and 145 K from both the transport and heat capacity in layered compound EuCu4As2 and SrCu4As2, respectively. The thermal expansion measurements present that the variations of the lattice parameters (ΔLab /Lab ) around TP , are significantly less than that for a typical crystalline phase transition. Our experimental results reveal that transition in EuCu4As2 and SrCu4As2 should be driven by subtle structural-distortion.

Keywords: distortion driven; lattice distortion; driven phase; distortion; subtle lattice; transition

Journal Title: Chinese Physics B
Year Published: 2023

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