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Effect of the orientation of Rydberg atoms on their collisional ionization cross section

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Collisional ionization between two Rydberg atoms in relative motion is examined. A classical trajectory Monte Carlo method is used to determine the cross sections associated with Penning ionization. The dependence… Click to show full abstract

Collisional ionization between two Rydberg atoms in relative motion is examined. A classical trajectory Monte Carlo method is used to determine the cross sections associated with Penning ionization. The dependence of the ionization cross section on the magnitude and the direction of orbital angular momentum of the electrons and the direction of the Laplace-Runge-Lenz vector of the electrons is studied. For a given magnitude of angular momentum, there can exist a difference of a factor of up to $\ensuremath{\sim}2.5$ in the ionization cross section between the orientations with the highest and the lowest ionization cross section. The case of exchange ionization is examined and its dependence on the magnitude of angular momentum is studied.

Keywords: collisional ionization; ionization cross; cross; ionization; cross section

Journal Title: Physical Review A
Year Published: 2020

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