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Rovibrational spin-averaged transitions in the hydrogen molecular ions

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We reconsider the calculation of rovibrational transition frequencies in hydrogen molecular ions. Some previously neglected contributions, such as the deuteron polarizability, are included into consideration in comparison with our previous… Click to show full abstract

We reconsider the calculation of rovibrational transition frequencies in hydrogen molecular ions. Some previously neglected contributions, such as the deuteron polarizability, are included into consideration in comparison with our previous work. In particular, one-loop and two-loop QED corrections at mα and mα orders are recalculated in the framework of the adiabatic approximation, with systematic inclusion of corrections associated with vibrational motion. Improved theoretical transitions frequencies are obtained and found to be in very good agreement with recent highprecision spectroscopy experiments in HD. New values for the mp/me and md/mp mass ratios are determined.

Keywords: molecular ions; spin averaged; averaged transitions; rovibrational spin; hydrogen molecular; transitions hydrogen

Journal Title: Physical Review A
Year Published: 2021

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