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Pre–Born-Oppenheimer Dirac-Coulomb-Breit computations for two-body systems

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The sixteen-component, no-pair Dirac--Coulomb--Breit equation, derived from the Bethe--Salpeter equation, is solved in a variational procedure using Gaussian-type basis functions for the example of positronium, muonium, hydrogen atom, and muonic… Click to show full abstract

The sixteen-component, no-pair Dirac--Coulomb--Breit equation, derived from the Bethe--Salpeter equation, is solved in a variational procedure using Gaussian-type basis functions for the example of positronium, muonium, hydrogen atom, and muonic hydrogen. The $\alpha$ fine-structure-constant dependence of the variational energies, through fitting a function of $\alpha^n$ and $\alpha^n\text{ln}\alpha$ terms, shows excellent agreement with the relevant energy expressions of the (perturbative) non-relativistic QED framework, and thereby, establishes a solid reference for the development of a computational relativistic QED approach.

Keywords: coulomb breit; pre born; dirac coulomb; born oppenheimer

Journal Title: Physical Review A
Year Published: 2023

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