LAUSR

Motivated by the poor understanding of the applicability of new exchange-correlation (XC) functionals to warm dense matter (WDM), we designed and performed multiple-shock reverberation compression experiments on dense krypton to evaluate explicitly the implications of recently derived XC functionals. The equation of states of krypton up to 155 GPa and 45 000 K, which ranges from an initial dense gaseous state up to the insulator-metal transition regime, were determined accurately. It is found that the experimental data are better reproduced by the strongly constrained and appropriately normed (SCAN) XC functional compared to the conventional Perdew-Burke-Ernzerhof and Van der Waals (vdW) DF1 functionals, elucidating that the introduction of the kinetic energy density and the intermediate-range vdW interaction is decisive. However, the incorporation of long-range interactions into the SCAN ($\mathrm{SCAN}+\mathrm{rVV}10$ XC functional) results in a noticeably stiffer prediction due to an overestimation of the density and internal energy of the system at low densities and temperatures. Our evaluation of the Karasiev-Sjostrom-Dufty-Trickey free-energy functional experimentally validates the XC thermal effect in the WDM regime, verifies the previous predictions, and sheds light on a direction for future theoretical efforts. Finally, a phase diagram of krypton is given, which provides a clear picture for understanding the thermophysical behavior of krypton in a wider temperature-pressure range.