LAUSR

We investigate, using a first-principles density-functional methodology, the nature of magnetism in monolayer 1T -phase of tantalum disulfide (1T -TaS2). Magnetism in the insulating phase of TaS2 is a longstanding puzzle and has led to a variety of theoretical proposals including notably the realization of a two-dimensional quantum-spin-liquid phase. By means of non-collinear spin calculations, we derive ab initio spin Hamiltonians including two-spin bilinear Heisenberg exchange, as well as biquadratic and four-spin ring-exchange couplings. We find that both quadratic and quartic interactions are consistently ferromagnetic, for all the functionals considered. Relativistic calculations predict substantial magnetocrystalline anisotropy. Altogether, our results suggest that this material may realize an easy-plane XXZ quantum ferromagnet with large anisotropy.