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Exciton dissociation mediated by phonons in organic photovoltaics

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It is well known that phonons can overscreen the bare Coulomb electron-electron repulsion, turning it into the effective attraction that binds the Cooper pairs responsible for BCS superconductivity. Here, we… Click to show full abstract

It is well known that phonons can overscreen the bare Coulomb electron-electron repulsion, turning it into the effective attraction that binds the Cooper pairs responsible for BCS superconductivity. Here, we use a simple lattice model to prove that the counterpart of this is also possible, whereby phonons overscreen the bare electron-hole attraction and may turn it repulsive at short distances, driving exciton dissociation in certain regions of the parameter space. We argue that this phonon-mediated short-range screening plays an important role in the physics of organic solar cell materials (and other materials with strong electron-phonon coupling) and could point the way to new strategies for optimizing their efficiencies.

Keywords: exciton dissociation; dissociation mediated; mediated phonons; phonons organic; electron

Journal Title: Physical Review B
Year Published: 2023

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