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Resonant inelastic x-ray scattering operators for t 2 g orbital systems

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We derive general expressions for resonant inelastic x-ray scattering (RIXS) operators for ${t}_{2g}$ orbital systems, which exhibit a rich array of unconventional magnetism arising from unquenched orbital moments. Within the… Click to show full abstract

We derive general expressions for resonant inelastic x-ray scattering (RIXS) operators for ${t}_{2g}$ orbital systems, which exhibit a rich array of unconventional magnetism arising from unquenched orbital moments. Within the fast collision approximation, which is valid especially for $4d$ and $5d$ transition metal compounds with short core-hole lifetimes, the RIXS operators are expressed in terms of total spin and orbital angular momenta of the constituent ions. We then map these operators onto pseudospins that represent spin-orbit entangled magnetic moments in systems with strong spin-orbit coupling. Applications of our theory to such systems as iridates and ruthenates are discussed, with a particular focus on compounds based on ${d}^{4}$ ions with Van Vleck-type nonmagnetic ground state.

Keywords: resonant inelastic; inelastic ray; operators orbital; orbital systems; ray scattering

Journal Title: Physical Review B
Year Published: 2017

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