We present numerical results for the tagged-particle dynamics by solving the mode-coupling theory in confined geometry for colloidal liquids (cMCT). We show that neither the microscopic dynamics nor the type… Click to show full abstract
We present numerical results for the tagged-particle dynamics by solving the mode-coupling theory in confined geometry for colloidal liquids (cMCT). We show that neither the microscopic dynamics nor the type of intermediate scattering function qualitatively changes the asymptotic dynamics in vicinity of the glass transition. In particular, we find similar characteristics of confinement in the low-frequency susceptibility spectrum which we interpret as footprints of parallel relaxation. We derive predictions for the localization length and the scaling of the diffusion coefficient in the supercooled regime and discover a pronounced nonmonotonic dependence on the confinement length. For dilute liquids in the hydrodynamic limit we calculate an analytical expression for the intermediate scattering functions, which is in perfect agreement with event-driven Brownian dynamics simulations. From this, we derive an expression for persistent anticorrelations in the velocity autocorrelation function (VACF) for confined motion. Using numerical results of the cMCT equations for the VACF we also identify a crossover between different scalings corresponding to a transition from unconfined to confined behavior.
               
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