LAUSR.org creates dashboard-style pages of related content for over 1.5 million academic articles. Sign Up to like articles & get recommendations!

Microscopic observation of hidden Johari-Goldstein-β process in glycerol.

Photo from wikipedia

The Johari-Goldstein-β (JG-β) process is widely observed in a variety of glass-forming systems and recognized as an intrinsic process in deeply supercooled and glassy states. However, in some systems, e.g.,… Click to show full abstract

The Johari-Goldstein-β (JG-β) process is widely observed in a variety of glass-forming systems and recognized as an intrinsic process in deeply supercooled and glassy states. However, in some systems, e.g., glycerol, a clear sign of the JG-β process is often not apparent; for example, an isolated JG-β peak may not be observed in the dielectric relaxation spectrum. In this study, we directly investigated the angstrom-scale dynamics of glycerol through quasielastic scattering experiments using time-domain interferometry. The relaxation times of the local motions start to decouple from the timescale of the diffusion process and follow the established behavior of the JG-β process. This finding microscopically indicates the existence of the hidden JG-β process in glycerol. In addition, we succeeded in determining the decoupling temperature of the JG-β process by using the spatial-scale selectivity of the quasielastic scattering technique.

Keywords: goldstein process; process glycerol; process; johari goldstein

Journal Title: Physical review. E
Year Published: 2022

Link to full text (if available)


Share on Social Media:                               Sign Up to like & get
recommendations!

Related content

More Information              News              Social Media              Video              Recommended



                Click one of the above tabs to view related content.