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Nonequilibrium phase transitions of a nematic liquid crystal under ac field-driven electroconvection.

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We report on phase transitions between isotropic and nematic liquid crystal phases in nonequilibrium systems (NESs). ac field-driven electroconvection (EC) provides an NES, which can be well controlled by the… Click to show full abstract

We report on phase transitions between isotropic and nematic liquid crystal phases in nonequilibrium systems (NESs). ac field-driven electroconvection (EC) provides an NES, which can be well controlled by the voltage V and frequency f; it arises electrohydrodynamically at a threshold voltage V_{c}. In continuous cooling and heating processes with various rates R, the critical temperature T_{c} was determined at a critical time t_{c} for phase transitions. Moreover, the morphological and dynamical features in the phase transitions were examined using an electro-optical image processing method. In comparison with an equilibrium system (V=0), two typical turbulent ECs (i.e., NESs), which are called dynamic scattering mode 1 (DSM1 for V>V_{c}) and DSM2 (for V≫V_{c}), were examined to understand the nonequilibrium phase transitions. In particular, our results show that in high voltage-induced turbulence (i.e., DSM2), T_{c} can be determined effectively without considering R; this provides a possibility for a material technology application in nonequilibrium-based circumstances.

Keywords: nonequilibrium; nematic liquid; liquid crystal; phase transitions; phase; field driven

Journal Title: Physical review. E
Year Published: 2022

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