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Depinning dynamics of confined colloidal dispersions under oscillatory shear.

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Strongly confined colloidal dispersions under shear can exhibit a variety of dynamical phenomena, including depinning transitions and complex structural changes. Here, we investigate the behavior of such systems under pure… Click to show full abstract

Strongly confined colloidal dispersions under shear can exhibit a variety of dynamical phenomena, including depinning transitions and complex structural changes. Here, we investigate the behavior of such systems under pure oscillatory shearing with shear rate γ[over ̇](t)=γ[over ̇]_{0}cos(ωt), as it is a common scenario in rheological experiments. The colloids' depinning behavior is assessed from a particle level based on trajectories, obtained from overdamped Brownian dynamics simulations. The numerical approach is complemented by an analytic one based on an effective single-particle model in the limits of weak and strong driving. Investigating a broad spectrum of shear rate amplitudes γ[over ̇]_{0} and frequencies ω, we observe complete pinning as well as temporary depinning behavior. We discover that temporary depinning occurs for shear rate amplitudes above a frequency-dependent critical amplitude γ[over ̇]_{0}^{crit}(ω), for which we attain an approximate functional expression. For a range of frequencies, approaching γ[over ̇]_{0}^{crit}(ω) is accompanied by a strongly increasing settling time. Above γ[over ̇]_{0}^{crit}(ω), we further observe a variety of dynamical structures, whose stability exhibits an intriguing (γ[over ̇]_{0},ω) dependence. This might enable new perspectives for potential control schemes.

Keywords: depinning dynamics; dynamics confined; confined colloidal; colloidal dispersions; dispersions oscillatory; shear rate

Journal Title: Physical review. E
Year Published: 2022

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