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Finite Temperature Green's Function Approach for Excited State and Thermodynamic Properties of Cool to Warm Dense Matter.

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We present a finite-temperature extension of the retarded cumulant Green's function for calculations of exited-state, correlation, and thermodynamic properties of electronic systems. The method incorporates a cumulant to leading order… Click to show full abstract

We present a finite-temperature extension of the retarded cumulant Green's function for calculations of exited-state, correlation, and thermodynamic properties of electronic systems. The method incorporates a cumulant to leading order in the screened Coulomb interaction W, and improves on the GW approximation of many-body perturbation theory. Results for the homogeneous electron gas are presented for a wide range of densities and temperatures, from cool to warm dense matter regimes, which reveal several hitherto unexpected properties. For example, correlation effects remain strong at high T while the exchange-correlation energy becomes small; also the spectral function broadens and damping increases with temperature, blurring the usual quasiparticle picture. These effects are evident, e.g., in Compton scattering which exhibits many-body corrections that persist at normal densities and intermediate T. The approach also yields exchange-correlation energies and potentials in good agreement with existing methods.

Keywords: finite temperature; thermodynamic properties; temperature; green function; function; cool warm

Journal Title: Physical review letters
Year Published: 2017

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