LAUSR.org creates dashboard-style pages of related content for over 1.5 million academic articles. Sign Up to like articles & get recommendations!

Cyclization and Relaxation Dynamics of Finite-Length Collapsed Self-Avoiding Polymers.

Photo from wikipedia

We study the cyclization and relaxation dynamics of ideal as well as interacting polymers as a function of chain length N. For the cyclization time τ_{cyc} of ideal chains we… Click to show full abstract

We study the cyclization and relaxation dynamics of ideal as well as interacting polymers as a function of chain length N. For the cyclization time τ_{cyc} of ideal chains we recover the known scaling τ_{cyc}∼N^{2} for different backbone models, for a self-avoiding slightly collapsed chain we obtain from Langevin simulations and scaling theory a modified scaling τ_{cyc}∼N^{5/3}. The cyclization and relaxation dynamics of a finite-length collapsed chain scale differently; this unexpected dynamic multiscale behavior is rationalized by the crossover between swollen and collapsed chain behavior.

Keywords: self avoiding; cyclization relaxation; relaxation dynamics; length

Journal Title: Physical review letters
Year Published: 2019

Link to full text (if available)


Share on Social Media:                               Sign Up to like & get
recommendations!

Related content

More Information              News              Social Media              Video              Recommended



                Click one of the above tabs to view related content.