We study the cyclization and relaxation dynamics of ideal as well as interacting polymers as a function of chain length N. For the cyclization time τ_{cyc} of ideal chains we… Click to show full abstract
We study the cyclization and relaxation dynamics of ideal as well as interacting polymers as a function of chain length N. For the cyclization time τ_{cyc} of ideal chains we recover the known scaling τ_{cyc}∼N^{2} for different backbone models, for a self-avoiding slightly collapsed chain we obtain from Langevin simulations and scaling theory a modified scaling τ_{cyc}∼N^{5/3}. The cyclization and relaxation dynamics of a finite-length collapsed chain scale differently; this unexpected dynamic multiscale behavior is rationalized by the crossover between swollen and collapsed chain behavior.
               
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