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Information-Theoretical Bound of the Irreversibility in Thermal Relaxation Processes.

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We establish that entropy production, which is crucial to the characterization of thermodynamic irreversibility, is obtained through a variational principle involving the Kulback-Leibler divergence. A simple application of this representation… Click to show full abstract

We establish that entropy production, which is crucial to the characterization of thermodynamic irreversibility, is obtained through a variational principle involving the Kulback-Leibler divergence. A simple application of this representation leads to an information-theoretical bound on entropy production in thermal relaxation processes; this is a stronger inequality than the conventional second law of thermodynamics. This bound is also interpreted as a constraint on the possible path of a thermal relaxation process in terms of information geometry. Our results reveal a hidden universal law inherent to general thermal relaxation processes.

Keywords: relaxation; theoretical bound; information theoretical; relaxation processes; thermal relaxation

Journal Title: Physical review letters
Year Published: 2019

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