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Order-Disorder Transitions in (Ca_{x}Sr_{1-x})_{3}Rh_{4}Sn_{13}.

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The classification of structural phase transitions as displacive or order-disorder in character is usually based on spectroscopic data above the transition. We use single crystal x-ray diffraction to investigate structural… Click to show full abstract

The classification of structural phase transitions as displacive or order-disorder in character is usually based on spectroscopic data above the transition. We use single crystal x-ray diffraction to investigate structural correlations in the quasiskutterudites, (Ca_{x}Sr_{1-x})_{3}Rh_{4}Sn_{13}, which have a quantum phase transition at x∼0.9. Three-dimensional pair distribution functions show that the amplitudes of local atomic displacements are temperature independent below the transition and persist to well above the transition, a signature of order-disorder behavior. The implications for the associated electronic transitions are discussed.

Keywords: disorder transitions; order disorder; order; transition

Journal Title: Physical review letters
Year Published: 2022

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