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Effective coordination numbers from EXAFS: general approaches for lanthanide and actinide dioxides

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New experimental EXAFS results for PuO2 and CeO2 nanoparticles in the size range of 2 nm were compared with published data for other lanthanide and actinide dioxides. A conceptual core-shell model… Click to show full abstract

New experimental EXAFS results for PuO2 and CeO2 nanoparticles in the size range of 2 nm were compared with published data for other lanthanide and actinide dioxides. A conceptual core-shell model with a calculated effective coordination number is proposed to fit the changes in EXAFS.

Keywords: effective coordination; actinide dioxides; coordination numbers; numbers exafs; lanthanide actinide

Journal Title: Journal of Synchrotron Radiation
Year Published: 2022

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