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Survey and analysis of crystal polymorphism in organic structures

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A comprehensive list of organic crystalline polymorphs has been assembled using the Cambridge Structural Database (CSD) and the structures categorized by crystal type, uncovering significant variations in the polymorphism prevalence… Click to show full abstract

A comprehensive list of organic crystalline polymorphs has been assembled using the Cambridge Structural Database (CSD) and the structures categorized by crystal type, uncovering significant variations in the polymorphism prevalence of each group. Phenomena such as the high prevalence of temperature-induced phase transitions in organic salts and the diminishing percentage of polymorphic crystal entries in the CSD over the last 20 years, with the exception of cocrystals, highlight areas of prospective study.

Keywords: organic structures; crystal polymorphism; analysis crystal; polymorphism organic; survey analysis; polymorphism

Journal Title: IUCrJ
Year Published: 2018

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