Racemic metallosupramolecular cages were fabricated from homochiral Ni(II)-based triple-stranded helicate building blocks. In hierarchical crystal packing, methyl groups of a cage can be accommodated in cone-shaped metal cluster metallocavitands of… Click to show full abstract
Racemic metallosupramolecular cages were fabricated from homochiral Ni(II)-based triple-stranded helicate building blocks. In hierarchical crystal packing, methyl groups of a cage can be accommodated in cone-shaped metal cluster metallocavitands of adjacent cages in the form of host–guest interactions.
               
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