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Hierarchical packing of racemic metallosupramolecular cages with Ni(II)-based triple-stranded helicate building blocks

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Racemic metallosupramolecular cages were fabricated from homochiral Ni(II)-based triple-stranded helicate building blocks. In hierarchical crystal packing, methyl groups of a cage can be accommodated in cone-shaped metal cluster metallocavitands of… Click to show full abstract

Racemic metallosupramolecular cages were fabricated from homochiral Ni(II)-based triple-stranded helicate building blocks. In hierarchical crystal packing, methyl groups of a cage can be accommodated in cone-shaped metal cluster metallocavitands of adjacent cages in the form of host–guest interactions.

Keywords: based triple; stranded helicate; racemic metallosupramolecular; helicate building; triple stranded; metallosupramolecular cages

Journal Title: IUCrJ
Year Published: 2023

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