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The FeIIIS2N2O2 chromophore of ammonium bis[salicylaldehyde thiosemicarbazonato(2−)]iron(III) contains two O,N,S-donating salicylaldehyde thiosemicarbazonate(2−) ligands in perpendicular planes, with the O and S atoms in cis and the N atoms in trans… Click to show full abstract
The FeIIIS2N2O2 chromophore of ammonium bis[salicylaldehyde thiosemicarbazonato(2−)]iron(III) contains two O,N,S-donating salicylaldehyde thiosemicarbazonate(2−) ligands in perpendicular planes, with the O and S atoms in cis and the N atoms in trans positions. The FeIII ion is in the low-spin state at 100 K. Systematic twinning by metric pseudomerohedry is explained by application of the order–disorder (OD) theory.
Keywords:
bis salicylaldehyde;
ammonium bis;
salicylaldehyde thiosemicarbazonato;
low spin
Journal Title: Acta Crystallographica. Section C, Structural Chemistry
Year Published: 2020
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Journal Title: Acta Crystallographica. Section C, Structural Chemistry
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!