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Structure and charge analysis of a cyclic aluminium hydride: cyclo-1,5-bis-μ-dimethylamino-3,7-di-μ-hydrido-2,4,6,8-tetrakis(dimethylaluminium)

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The title compound crystallizes as eight-membered rings with –(CH3)2Al–(CH3)2N–(CH3)2Al– moieties connected by single hydride bridges. The molecular structures and partial atomic charges determined both by X-ray methods and by DFT… Click to show full abstract

The title compound crystallizes as eight-membered rings with –(CH3)2Al–(CH3)2N–(CH3)2Al– moieties connected by single hydride bridges. The molecular structures and partial atomic charges determined both by X-ray methods and by DFT calculations are compared.

Keywords: charge analysis; structure charge; analysis cyclic; hydride; aluminium hydride; cyclic aluminium

Journal Title: Acta Crystallographica. Section C, Structural Chemistry
Year Published: 2023

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