Three new 3-amino-2H-azirine derivatives have been synthesized as racemates or mixtures of diastereoisomers. Comparison of their crystal structures with those of the 11 other 3-amino-2H-azirines in the literature reveal that… Click to show full abstract
Three new 3-amino-2H-azirine derivatives have been synthesized as racemates or mixtures of diastereoisomers. Comparison of their crystal structures with those of the 11 other 3-amino-2H-azirines in the literature reveal that the formal N—C single bond in the azirine ring is consistently long at around 1.57 Å.
               
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