Photo by livvie_bruce from unsplash
Pyridine-4-thiol has been explored as an acceptor for a halogen-bond (HaB) interaction. For this compound, it is the S atom instead of the pyridine group that is the moiety of… Click to show full abstract
Pyridine-4-thiol has been explored as an acceptor for a halogen-bond (HaB) interaction. For this compound, it is the S atom instead of the pyridine group that is the moiety of choice for establishing the interactions, producing a betaine-type structure. Interestingly, when left in solution, this compound forms a methylene-bridged sulfide that implies the activation of the CH2Cl2 solvent. The pre-organization imposed by the HaB seems to have a clear influence on the outcome.
Keywords:
halogen bond;
bond hab;
pyridine thiol;
hab
Journal Title: Acta Crystallographica. Section C, Structural Chemistry
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Acta Crystallographica. Section C, Structural Chemistry
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!