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Crystal structures of (E)-4-[1-(2-carbamothioylhydrazinylidene)ethyl]phenyl acetate and (E)-4-[1-(2-carbamothioylhydrazinylidene)ethyl]phenyl benzoate

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In the title compounds, the thiosemicarbazone group adopts an extended conformation, and there is a short N—H⋯N contact present forming an S(5) ring motif. In the crystals of both compounds,… Click to show full abstract

In the title compounds, the thiosemicarbazone group adopts an extended conformation, and there is a short N—H⋯N contact present forming an S(5) ring motif. In the crystals of both compounds, molecules are linked by pairs of N—H⋯S hydrogen bonds, forming dimers with (8) ring motifs.

Keywords: structures carbamothioylhydrazinylidene; crystal structures; carbamothioylhydrazinylidene ethyl; phenyl acetate; ethyl phenyl

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2017

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