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Crystal structure of bis[cis-(1,4,8,11-tetraazacyclotetradecane-κ4 N)bis(thiocyanato-κN)chromium(III)] dichromate monohydrate from synchrotron X-ray diffraction data

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The asymmetric unit of the title compound comprises of one complex cation, one half of a Cr2O7 2− anion and one half of a water molecule. The CrIII ion has… Click to show full abstract

The asymmetric unit of the title compound comprises of one complex cation, one half of a Cr2O7 2− anion and one half of a water molecule. The CrIII ion has a distorted octahedral coordination by four N atoms of the cyclam ligand and by two N-bonded NCS groups in cis positions; the conformation of the dichromate anion is staggered.

Keywords: crystal structure; cis tetraazacyclotetradecane; dichromate; bis cis; bis; structure bis

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2017

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