A new arsenate K1 + 2xNi1 - xFe2(AsO4)3 (x = 1/8) was synthesized using a flux method and its crystal structure was determined from single-crystal X-ray diffraction data. It appears… Click to show full abstract
A new arsenate K1 + 2xNi1 - xFe2(AsO4)3 (x = 1/8) was synthesized using a flux method and its crystal structure was determined from single-crystal X-ray diffraction data. It appears closely related to the α-CrPO4 structure type. The proposed structural model was validated by bond-valence-sum calculations, charge-distribution and Madelung energy analyses
               
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