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C 2-isomer of [Pd(tfd)]6 [tfd is S2C2(CF3)2] as its benzene solvate: a new member of the small but growing class of homoleptic palladium(II) monodithiolenes in the form of hexameric cubes

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S 6- and C 2-symmetric structure types are possible for homoleptic palladium monodithiolenes in the form of hexameric cubes. The C 2-isomer of [Pd(S2C2(CF3)2)]6 is described here and the question… Click to show full abstract

S 6- and C 2-symmetric structure types are possible for homoleptic palladium monodithiolenes in the form of hexameric cubes. The C 2-isomer of [Pd(S2C2(CF3)2)]6 is described here and the question of whether additional isomers are possible is answered.

Keywords: homoleptic palladium; tfd; monodithiolenes form; palladium monodithiolenes; form hexameric; hexameric cubes

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2017

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