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Crystal structure and Hirshfeld surface analysis of hexakis(μ-benzoato-κ2 O:O′)bis(pyridine-3-carbonitrile-κN 1)trizinc(II)

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The asymmetric unit of the title complex contains one half of the complex molecule, one and a half ZnII cations, three benzoate (Bnz) and one pyridine-3-carbonitrile (CPy) molecule; the Bnz… Click to show full abstract

The asymmetric unit of the title complex contains one half of the complex molecule, one and a half ZnII cations, three benzoate (Bnz) and one pyridine-3-carbonitrile (CPy) molecule; the Bnz anions act as bidentate ligands through the carboxylate O atoms, while the Cpy anion acts as a monodentate N(pyridine)-bonding ligand. The complete centrosymmetric trinuclear complex thus comprises a linear array of three ZnII cations. In the crystal, the Bnz anions link to the Cpy N atoms via weak C—H⋯N hydrogen bonds, forming a two-dimensional network. The Hirshfeld surface analysis confirms the role of H-atom contacts in establishing the packing.

Keywords: pyridine carbonitrile; hirshfeld surface; pyridine; surface analysis

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2017

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