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Crystal structure of hexakis(dimethyl sulfoxide-κO)cobalt(II) bis[trichlorido(quinoline-κN)cobaltate(II)]

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Anhydrous cobalt(II) chloride reacts with quinoline (C9H7N) in dimethyl sulfoxide (Me2SO) to form the novel complex salt [CoII(Me2SO)6][CoIICl3quinoline]2. The compound comprises an octahedral homoleptic Me2SO-solvated cobalt(II) cation and a tetrahedral… Click to show full abstract

Anhydrous cobalt(II) chloride reacts with quinoline (C9H7N) in dimethyl sulfoxide (Me2SO) to form the novel complex salt [CoII(Me2SO)6][CoIICl3quinoline]2. The compound comprises an octahedral homoleptic Me2SO-solvated cobalt(II) cation and a tetrahedral cobaltate(II) anion attached to three chloro ligands and one quinoline moiety.

Keywords: dimethyl sulfoxide; quinoline; cobalt; cobaltate

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2018

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