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Crystal structures and Hirshfeld surface analyses of (N-hexyl-N-methyldithiocarbamato-κ2 S,S′)triphenyltin(IV) and [N-methyl-N-(2-phenylethyl)dithiocarbamato-κ2 S,S′]triphenyltin(IV)

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The metal coordination geometry in each of the title molecules, [Sn(C6H5)3(C8H16NS2)] (I) and [Sn(C6H5)3(C10H12NOS2)] (II), is based on a heavily distorted tetrahedron owing to the asymmetric mode of coordination of… Click to show full abstract

The metal coordination geometry in each of the title molecules, [Sn(C6H5)3(C8H16NS2)] (I) and [Sn(C6H5)3(C10H12NOS2)] (II), is based on a heavily distorted tetrahedron owing to the asymmetric mode of coordination of the dithiocarbamate ligand. The persence of C—H⋯π(phenyl) interactions in the crystals lead to dimeric aggregates in (I) and supramolecular chains (II).

Keywords: surface analyses; triphenyltin; hirshfeld surface; analyses hexyl; structures hirshfeld; crystal structures

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2018

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