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Redetermination of the crystal structure of bis(tri-2-pyridylamine)iron(II) bis(perchlorate), and a new refinement of the isotypic nickel(II) analogue: treatment of the perchlorate anion disorder

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The crystal structure of bis(tri-2-pyridylamine)iron(II) bis(perchlorate) has been redetermined, and that of the isotypic bis(tri-2-pyridylamine)nickel(II) bis(perchlorate) complex has been rerefined. In each case, the perchlorate anion is disordered over four… Click to show full abstract

The crystal structure of bis(tri-2-pyridylamine)iron(II) bis(perchlorate) has been redetermined, and that of the isotypic bis(tri-2-pyridylamine)nickel(II) bis(perchlorate) complex has been rerefined. In each case, the perchlorate anion is disordered over four sets of atomic sites, and the ions are linked by C—H⋯O hydrogen bonds to form a supramolecular three-dimensional framework.

Keywords: tri pyridylamine; bis perchlorate; perchlorate; bis tri; bis

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2018

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