The crystal structure of bis(tri-2-pyridylamine)iron(II) bis(perchlorate) has been redetermined, and that of the isotypic bis(tri-2-pyridylamine)nickel(II) bis(perchlorate) complex has been rerefined. In each case, the perchlorate anion is disordered over four… Click to show full abstract
The crystal structure of bis(tri-2-pyridylamine)iron(II) bis(perchlorate) has been redetermined, and that of the isotypic bis(tri-2-pyridylamine)nickel(II) bis(perchlorate) complex has been rerefined. In each case, the perchlorate anion is disordered over four sets of atomic sites, and the ions are linked by C—H⋯O hydrogen bonds to form a supramolecular three-dimensional framework.
               
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