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Crystal structure of (E)-N'-[1-(4-amino-phen-yl)ethyl-idene]-2-hy-droxy-5-iodo-benzohydrazide methanol monosolvate.

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In the title compound, C15H14IN3O2·CH3OH, two aromatic rings are linked by an N-substituted hydrazide function. The dihedral angle between the aromatic rings is 10.53 (8)°. The stereochemistry about the imine function… Click to show full abstract

In the title compound, C15H14IN3O2·CH3OH, two aromatic rings are linked by an N-substituted hydrazide function. The dihedral angle between the aromatic rings is 10.53 (8)°. The stereochemistry about the imine function is E. The methanol mol­ecule forms an O—H⋯O hydrogen bond to the hydrazide O atom. In the crystal, chains of mol­ecules running along the c-axis direction are formed by O—H⋯O hydrogen bonds. Adjacent chains are linked through N—H⋯O hydrogen bonds and π–π stacking inter­actions. The inter­molecular inter­actions in the crystal packing were investigated using Hirshfeld surface analysis, which indicated that the most significant contacts are H⋯H (38.2%), followed by C⋯H/H⋯C (20.6%), O⋯H/H⋯O (11.1%) and I⋯H/H⋯I (9.7%).

Keywords: crystal structure; methanol; structure amino; phen ethyl; ethyl idene; amino phen

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2018

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