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Crystal structure of poly[[hexaaquatris(μ-3,6-dioxocyclohexa-1,4-diene-1,4-diolato)dierbium(III)] octadecahydrate]

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The title lanthanide complex is isostructural with its La, Gd, Yb and Lu analogues. The Er3+ ion, located on a threefold rotation axis, is nine-coordinated in a distorted tricapped trigonal–prismatic… Click to show full abstract

The title lanthanide complex is isostructural with its La, Gd, Yb and Lu analogues. The Er3+ ion, located on a threefold rotation axis, is nine-coordinated in a distorted tricapped trigonal–prismatic geometry, which is completed by six oxygen atoms from three dhbq2− ligands and three oxygen atoms from coordinated water molecules. Each dhbq2− ligand acts as a μ2-bis(bidentate) bridging mode to connect two Er3+ ions to form honeycomb (6,3) two-dimensional sheets extending in the ab plane.

Keywords: hexaaquatris dioxocyclohexa; poly hexaaquatris; structure poly; crystal structure; dioxocyclohexa diene; diene diolato

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2019

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