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The reduction of CoBr2 by the Grignard reagent p-tolylmagnesium bromide in the presence of 1,2-bis(diphenylphosphanyl)benzene (dbpz) resulted in the d 10, formally Co−1 anion, [Co(dpbz)2]−. The crystal structure of the… Click to show full abstract
The reduction of CoBr2 by the Grignard reagent p-tolylmagnesium bromide in the presence of 1,2-bis(diphenylphosphanyl)benzene (dbpz) resulted in the d 10, formally Co−1 anion, [Co(dpbz)2]−. The crystal structure of the [MgBr(THF)5]+ (THF is tetrahydrofuran) salt showed the anion to be pseudotetrahedral and packed in alternating layers of anions and cations.
Keywords:
bis diphenylphosphanyl;
bis;
diphenylphosphanyl benzene;
crystal structure;
tetrahydrofuran
Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2019
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Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!