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N-[2-(Trifluoromethyl)phenyl]maleamic acid: crystal structure and Hirshfeld surface analysis

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The –COOH group of the title compound adopts a syn conformation (O= C—O—H = 0°) unlike the anti conformation observed in related maleamic acids. This is correlated with the formation… Click to show full abstract

The –COOH group of the title compound adopts a syn conformation (O= C—O—H = 0°) unlike the anti conformation observed in related maleamic acids. This is correlated with the formation of carboxylic acid inversion dimers linked by pairwise O—H⋯O hydrogen bonds in the crystal of the title compound rather than an intramolecular O—H⋯O hydrogen bond.

Keywords: acid crystal; phenyl maleamic; structure hirshfeld; trifluoromethyl phenyl; maleamic acid; crystal structure

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2019

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