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Different electron configurations for ZnII (d 10) and NiII (d 8) lead to less regular coordination environments for the former: ZnII adopts strongly distorted octahedral or even fivefold coordination spheres… Click to show full abstract
Different electron configurations for ZnII (d 10) and NiII (d 8) lead to less regular coordination environments for the former: ZnII adopts strongly distorted octahedral or even fivefold coordination spheres whereas NiII favours rather regular octahedra. As a consequence, only the more flexible zinc cations may act as nodes in two-dimensional extended structures.
Keywords:
pyridine dicarboxylates;
crystal field;
stabilization matters;
field stabilization;
dicarboxylates crystal;
complexes pyridine
Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2019
Link to full text (if available)
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Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!