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(E)-6,6′-(Diazene-1,2-diyl)bis(1,10-phenanthrolin-5-ol) trichloromethane disolvate: a superconjugated ligand

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The preparation and structural characterization of the diazo-diphenanthroline compound, (E)-6,6′-(diazene-1,2-diyl)bis(1,10-phenanthrolin-5-ol) are described. The fully conjugated bis-phenanthroline molecule is expected to offer exciting new physical and chemical properties, and should form… Click to show full abstract

The preparation and structural characterization of the diazo-diphenanthroline compound, (E)-6,6′-(diazene-1,2-diyl)bis(1,10-phenanthrolin-5-ol) are described. The fully conjugated bis-phenanthroline molecule is expected to offer exciting new physical and chemical properties, and should form the basis of novel metal coordination complexes as a consequence of the dual N,N′-1,10-phenanthroline chelating moieties situated on the opposite ends of the molecule.

Keywords: diyl bis; bis phenanthrolin; diazene diyl; phenanthrolin trichloromethane; bis

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2019

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