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Crystal structure of (15,20-bis(2,3,4,5,6-pentafluorophenyl)-5,10-{(pyridine-3,5-diyl)bis[(sulfanediylmethylene)[1,1′-biphenyl]-4′,2-diyl]}porphyrinato)nickel(II) dichloromethane x-solvate (x > 1/2) showing a rare CN5 coordination

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The crystal structure of the title compound consists of discrete complexes with a five-coordinate Ni cation and intramolecular hydrogen-bonded dichloromethane solvent molecules that are linked into dimers via pairs of… Click to show full abstract

The crystal structure of the title compound consists of discrete complexes with a five-coordinate Ni cation and intramolecular hydrogen-bonded dichloromethane solvent molecules that are linked into dimers via pairs of intermolecular C—H⋯S hydrogen bonds.

Keywords: diyl; structure bis; dichloromethane; crystal structure; bis

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2019

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