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Crystal structure and Hirshfeld surface analysis of (E)-3-[(4-chlorobenzylidene)amino]-5-phenylthiazolidin-2-iminium bromide

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In the crystal of the title salt, the cations and anions are linked via N—H⋯Br hydrogen bonds. In the 1H NMR spectra of this compound, the NH iminium protons are… Click to show full abstract

In the crystal of the title salt, the cations and anions are linked via N—H⋯Br hydrogen bonds. In the 1H NMR spectra of this compound, the NH iminium protons are observed at δ = 10.46 p.p.m., which confirms the strong charge-assisted hydrogen bonding (CAHB) in the =HN+—H⋯Br− synthon.

Keywords: iminium; surface analysis; hirshfeld surface; analysis chlorobenzylidene; structure hirshfeld; crystal structure

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2019

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