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Crystal structure, Hirshfeld surface analysis and PIXEL calculations of a 1:1 epimeric mixture of 3-[(4-nitrobenzylidene)amino]-2(R,S)-(4-nitrophenyl)-5(S)-(propan-2-yl)imidazolidin-4-one

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A 1:1 epimeric mixture of 2(R,S)-(4-nitrophenyl)-3-[(4-nitrobenzylidene)amino]-5(S)-(propan-2-yl)imidazolidin-4-one was derived from an initial reaction of 2(S)-amino-3-methyl-1-oxobutanehydrazine at its hydrazine moiety to provide a 4-nitrobenzylidine derivative, followed by a cyclization reaction with another… Click to show full abstract

A 1:1 epimeric mixture of 2(R,S)-(4-nitrophenyl)-3-[(4-nitrobenzylidene)amino]-5(S)-(propan-2-yl)imidazolidin-4-one was derived from an initial reaction of 2(S)-amino-3-methyl-1-oxobutanehydrazine at its hydrazine moiety to provide a 4-nitrobenzylidine derivative, followed by a cyclization reaction with another molecule of 4-nitrobenzaldehyde to form the chiral five-membered imidazolidin-4-one ring.

Keywords: imidazolidin one; amino; epimeric mixture; nitrobenzylidene amino; propan imidazolidin

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2019

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