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1-Ethyl 2-methyl 3,4-bis(acetyloxy)pyrrolidine-1,2-dicarboxylate: crystal structure, Hirshfeld surface analysis and computational chemistry

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The tetra-substituted pyrrolidine ring in the title compound has a twisted conformation about the central C—C bond with the N-bound ethylcarboxylate group in an equatorial position and the remaining substituents… Click to show full abstract

The tetra-substituted pyrrolidine ring in the title compound has a twisted conformation about the central C—C bond with the N-bound ethylcarboxylate group in an equatorial position and the remaining substituents in axial positions. In the crystal, methyl- and methylene-C—H⋯O(carbonyl) interactions involving all four carbonyl-O atoms lead to supramolecular double-layers.

Keywords: bis acetyloxy; acetyloxy pyrrolidine; methyl bis; ethyl methyl; chemistry; pyrrolidine dicarboxylate

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2020

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