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The investigation of the coordination chemistry of rare-earth metal complexes with cyanide ligands led to the isolation and crystallographic characterization of the Ln III cyanotriphenylborate complexes, LnCl2(THF)4(NCBPh3) (Ln = Dy,… Click to show full abstract
The investigation of the coordination chemistry of rare-earth metal complexes with cyanide ligands led to the isolation and crystallographic characterization of the Ln III cyanotriphenylborate complexes, LnCl2(THF)4(NCBPh3) (Ln = Dy, Y) as well as the cyanoborates [NEt4][B3(μ-O)3(C6H5)4], [NEt4][NCBPh2(μ-O)BPh2], [K(crypt)]2[B3(μ-O)3(C6H5)4][NCBPh2Me]. The [NCBPh2(μ-O)BPh2]1− and (NCBPh2Me)1− anions have not been structurally characterized previously.
Keywords:
cyanotriphenylborate complexes;
bph2;
ncbph2 bph2;
rare earth;
ncbph2me ncbph2;
crystallographic characterization
Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2021
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Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!