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Synthesis and crystal structure of a heterobimetallic cadmium–sodium complex of 1,3,5-triazine-2,4,6-trione, [CdNa2(C3H2N3O3)4(H2O)8]

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In the heterobimetallic cadmium–sodium complex, heptaaqua-1κ3 O,2κ2 O,3κ2 O-bis(μ-4,6-dioxo-1,4,5,6-tetrahydro-1,3,5-triazin-2-olato)-1:2κ2 O 2:N 1;2:3κ2 N 1:O 2-bis(4,6-dioxo-1,4,5,6-tetrahydro-1,3,5-triazin-2-olato)-1κO 2,3κO 2-2-cadmium-1,3-disodium, the ligand coordination around the Cd and Na atoms leads to the formation… Click to show full abstract

In the heterobimetallic cadmium–sodium complex, heptaaqua-1κ3 O,2κ2 O,3κ2 O-bis(μ-4,6-dioxo-1,4,5,6-tetrahydro-1,3,5-triazin-2-olato)-1:2κ2 O 2:N 1;2:3κ2 N 1:O 2-bis(4,6-dioxo-1,4,5,6-tetrahydro-1,3,5-triazin-2-olato)-1κO 2,3κO 2-2-cadmium-1,3-disodium, the ligand coordination around the Cd and Na atoms leads to the formation of a two-dimensional coordination polymer in the (110) plane, which is supported by means of a variety of N—H⋯O, O—H⋯O and O—H⋯N intermolecular and intramolecular interactions owing to different substitution patterns.

Keywords: heterobimetallic cadmium; synthesis crystal; cadmium; cadmium sodium; sodium complex

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2021

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