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Crystal structure of a trigonal polymorph of aquadioxidobis(pentane-2,4-dionato-κ2 O,O′)uranium(VI)

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[UO2(acac)2(H2O)] is constructed from one uranyl(VI) unit, two monoanionic acetylacetonate (acac) ligands and one aqua ligand. The U atom exhibits a UO7 distorted pentagonal–bipyramidal coordination geometry; four O atoms from… Click to show full abstract

[UO2(acac)2(H2O)] is constructed from one uranyl(VI) unit, two monoanionic acetylacetonate (acac) ligands and one aqua ligand. The U atom exhibits a UO7 distorted pentagonal–bipyramidal coordination geometry; four O atoms from two chelating bidentate acac ligands and one O atom of a aquo ligand (Ow) form the equatorial plane while two uranyl(VI) O atoms are located at the axial positions.

Keywords: structure trigonal; polymorph aquadioxidobis; trigonal polymorph; crystal structure; pentane dionato; aquadioxidobis pentane

Journal Title: Acta Crystallographica Section E: Crystallographic Communications
Year Published: 2022

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